Nanoindentation Testing of the Microstructure of AZ91 Alloy Castings with a WCCoCr Coating

Authors

DOI:

https://doi.org/10.24425/afe.2026.158027

Abstract

The paper presents the results of nanoindentation testing of AZ91 magnesium alloy and a WCCoCr coating deposited by Air Plasma Spraying (APS). In order to determine the material properties of individual components of the microstructure of the AZ91 alloy and the WCCoCr coating, i.e., Vickers hardness – HVIT, indentation hardness – HIT, and indentation modulus - EIT, nanoindentation testing of the individual microstructural components of the AZ91 alloy and the WCCoCr coating was performed. The analysis showed significant differences in material property values between the α-Mg matrix, the γ-Mg17(Al,Zn)12 intermetallic phase, the β(α+γ) eutectic, and the WCCoCr coating. The highest values of indentation hardness and indentation modulus were found in the case of the microstructure (grains) of the WCCoCr coating. The obtained results indicate that the application of the WCCoCr coating significantly improves the tribological properties of the surface layer of AZ91 alloy castings, especially scratch resistance. The results of these tests complement the previously performed scratch tests of the WCCoCr coating.

References

[1] Lai, L., Wu, H., Mao, G., Li, Z., Zhang, L. & Liu, Q. (2022). Microstructure and corrosion resistance of two-dimensional TiO2/MoS2 hydrophobic coating on AZ31B magnesium alloy. Coatings. 12(10), 1488, 1-12. DOI: 10.3390/coatings12101488.

[2] Yang, Y., Xiong, X., Chen, J., Peng, X., Chen, D. & Pan, F. (2021). Research advances in magnesium and magnesium alloys worldwide in 2020. Journal of Magnesium and Alloys. 9(3), 705-747. DOI: 10.1016/j.jma.2021.04.001.

[3] Xi, B., Fang, G. & Xu, S. (2018). Multiscale mechanical behavior and microstructure evolution of extruded magnesium alloy sheets: experimental and crystal plasticity analysis. Materials Characterization. 135, 115-123. DOI: 10.1016/j.matchar.2017.11.034.

[4] Wang G.G. & Weiler J.P. (2023). Recent developments in high pressure die-cast magnesium alloys for automotive and future applications. Journal of Magnesium and Alloys. 11(1), 78-87. DOI: 10.1016/j.jma.2022.10.001.

[5] Liu B., Yang J., Zhang X., Yang Q., Zhang J. & Li X. (2022). Development and application of magnesium alloy parts for automotive OEMs: A review. Journal of Magnesium and Alloys. 11(1), 15-47. DOI: 10.1016/j.jma.2022.12.015.

[6] Xu, T., Yang, Y., Peng, X., Song, J. & Pan, F. (2019). Overview of advancement and development trend on magnesium alloy. Journal of Magnesium and Alloys. 7(3), 536-544. DOI: 10.1016/j.jma.2019.08.001.

[7] Prasad, S.S., Prasad, S.B., Verma, K., Mishra, R.K., Kumar, V. & Singh, S. (2022). The role and significance of magnesium in modern day research-A review. Journal of Magnesium and alloys. 10(1), 1-61. DOI: 10.1016/j.jma.2021.05.012.

[8] Ramalingam, V.V., Ramasamy, P., Kovukkal, M.D. & Myilsamy, G. (2020). Research and development in magnesium alloys for industrial and biomedical applications: a review. Metals and Materials International. 26(4), 409-430. DOI: 10.1007/s12540-019-00346-8.

[9] Tan, J. & Ramakrishna, S. (2021). Applications of magnesium and its alloys: A review. Applied Sciences. 11(15), 6861, 1-16. DOI: 10.3390/app11156861.

[10] Rakoch, A.G., Monakhova, E.P., Khabibullina, Z.V., Serdechnova, M., Blawert, C., Zheludkevich, M.L. & Gladkova, A.A. (2020). Plasma electrolytic oxidation of AZ31 and AZ91 magnesium alloys: Comparison of coatings formation mechanism. Journal of Magnesium and Alloys. 8(3), 587-600. DOI: 10.1016/j.jma.2020.06.002.

[11] Morelli, S., Rombolà, G., Bolelli, G., Lopresti, M., Puddu, P., Boccaleri, E., Seralessandri, L., Palin, L. Testa, V. & Lusvarghi, L. (2022). Hard ultralight systems by thermal spray deposition of WC-CoCr onto AZ31 magnesium alloy. Surface and Coatings Technology. 451, 129056, 1-26. DOI: 10.1016/j.surfcoat.2022.129056.

[12] Buchtík, M., Vyklický O., Filipenský, J., Wasserbauer, J. & Ptáček P. (2019). Microstructural characterization and wear behavior of WC-CoCr coating on AZ91 magnesium alloy. Proceedings of the Metal. 922-927.

[13] Jonda, E., Łatka, L., Tomiczek, A., Godzierz, M., Pakieła, W. & Nuckowski, P. (2021). Microstructure investigation of WC-based coatings prepared by HVOF onto AZ31 substrate. Materials. 15(1), 40, 1-15. DOI: 10.3390/ma15010040.

[14] García-Rodríguez, S., López, A. J., Bonache, V., Torres, B. & Rams, J. (2020). Fabrication, Wear, and corrosion resistance of HVOF sprayed WC-12Co on ZE41 magnesium alloy. Coatings. 10(5), 502, 1-21. DOI:10.3390/coatings10050502.

[15] Shen, J., Zou, B., Dong, S., Cai, X. & Cao, X. (2019). Fabrication and characterization of TiB2-TiC-Co wear-resistant coatings on AZ91D magnesium alloy. Surface and Coatings Technology. 364, 358-368. DOI: 10.1016/j.surfcoat.2019.02.090.

[16] Kubatík, T.F., Lukáč, F., Stoulil, J., Ctibor, P., Průša, F. & Stehlíková, K. (2017). Preparation and properties of plasma sprayed NiAl10 and NiAl40 coatings on AZ91 substrate. Surface and Coatings Technology. 319, 145-154. DOI: 10.1016/j.surfcoat.2017.03.064.

[17] Mróz, M., Olszewska, S. & Rąb, P. (2023): Evaluation of the possibility to improve the scratch resistance of the AZ91 alloy by applying a coating. Archives of Foundry Engineering. 23(4), 157-162. DOI: 10.24425/afe.2023.146690.

Downloads

Published

2026-09-21

How to Cite

Olszewska, S., and M.F. Mróz. “Nanoindentation Testing of the Microstructure of AZ91 Alloy Castings With a WCCoCr Coating”. Archives of Foundry Engineering, Sept. 2026, doi:10.24425/afe.2026.158027.

Issue

Section

Articles