The Effect of Heat Treatment on the Microstructure and Hardness of an Austenitic Matrix of High-Manganese Cast Steel with the Addition of Molybdenum

Authors

DOI:

https://doi.org/10.24425/afe.2025.155351

Abstract

The greatest influence on the wear of tool steel has its microstructure, which depends on the chemical composition and heat treatment. The presence of carbides in the alloy matrix is not always desirable and can have an adverse effect on the wear mechanism of this material, resulting in the formation of stresses and even cracks during operation. Therefore, it is necessary to apply heat treatment, which makes the microstructure homogeneous or allows for the precipitation of secondary carbides strengthening the matrix. The main aim of this study is to examine the effect of molybdenum addition on the structure and microhardness of high-manganese cast steel in the as-cast state and after heat treatment. The as-cast microstructure consists of a high-manganese austenitic matrix with molybdenum carbides and alloy ledeburite distributed at grain boundaries. As a result of solution heat treatment, only the alloy ledeburite is dissolved. The result of aging is not the precipitation of secondary molybdenum carbides but of alloy cementite. Raising the temperature or extending the time of solution heat treatment changes the hardness of austenite to a very small degree only, and the decrease in hardness becomes less significant with the increasing addition of molybdenum. Extending the tempering time has a similar effect, and changes in the hardness decrease are less pronounced.

References

[1] Tęcza, G. & Garbacz-Klempka, A. (2016). Microstructure of cast high-manganese steel containing titanium. Archives of Foundry Engineering. 16(4), 163-168. DOI: 10.1515/afe-2016-0103.

[2] Dziubek, M., Rutkowska-Gorczyca, M., Dudziński, W. & Grygier, D. (2022). Investigation into changes of microstructure and abrasive wear resistance occurring in high manganese steel X120Mn12 during isothermal annealing and re-austenitisation process. Materials. 15(7), 2622, 1-16. DOI: 10.3390/ma15072622.

[3] Mohammadnezhad, M., Javaheri, V. & Naseri, M. (2013) Effect of the molybdenum on the microstructural and mechanical properties of hadfield austenitic manganese steel. In the Second International Iranian Metallurgical Engineering and Iranian Fundrymen Scientific Society, 30-31 October 2013 (Vol. 12816, pp. 1-7). Semnan, Iran.

[4] Dziubek, M., Rutkowska-Gorczyca, M. & Grygier, D. (2023). The effect of the austenitisation temperature for the two-stage heat treatment of high-manganese steels on its wear resistance under abrasive conditions. Tribologia. 305(3), 19-29. DOI: 10.5604/01.3001.0053.9426.

[5] Kalandyk, B., Tęcza, G., Zapała, R. & Sobula, S. (2015). Cast High-Manganese Steel – the Effect of Microstructure on Abrasive Wear Behaviour in Miller Test. Archives of Foundry Engineering. 15(2), 35-38. DOI: 10.1515/afe-2015-0033.

[6] Gürol, U. & Can Kurnaz, S. (2020). Effect of carbon and manganese content on the microstructure and mechanical properties of high manganese austenitic steel. Journal of Mining and Metallurgy Section B Metallurgy. 56(2), 171-182. DOI: 10.2298/JMMB191111009G.

[7] Fuoco, R., Todorov, D., Cavalcanti, A.H. & Santos, N.L. (2012) Effect of chemical composition on the carbide reprecipitation kinetics of hadfield austenitic manganese steel. Transactions of the American Foundry Society. 120, 507-522.

[8] Tęcza, G. & Sobula, S. (2013). Effect of heat treatment on change microstructure of cast high-manganese hadfield steel with elevated chromium content. Archives of Foundry Engineering. 13(3), 67-70.

[9] Berkowski, L., Borowski, J. & Rybak, Z. (2009). Strengthening of the steel after heat treating with the matrix of different structure. Journal of Research and Application in Agriculture Engineering. 54(2), 9-15. (in Polish)

[10] Olawale, O., Ibitoye, S. & Shittu, M.D. (2013). Workhardening behaviour and microstructural analysis of failed austenitic manganese steel crusher jaws. Materials Research. 16(6), 1274-1281. DOI: 10.1590/S1516-14392013005000144.

[11] Ham, Y.S., Kim, J.T., Kwak, S.Y., Choi, J.K. & Yoon, W.Y. (2010). Critical cooling rate on carbide precipitation during quenching of austenitic manganese steel. China Foundry. 7(2), 178-182.

[12] Jabłońska, M., Śmiglewicz, A., Niewielski, G. & Hetmańczyk, M. (2011). Heat treatment of high manganese type X57MnAl27-5 austenitic steel. IOP Conference Series Materials Science and Engineering. 22(1), 012014, 1-6. DOI: 10.1088/1757-899X/22/1/012014.

[13] Tęcza, G. & Zapała, R. (2018). Changes in impact strength and abrasive wear resistance of cast high manganese steel due to the formation of primary titanium carbides. Archives of Foundry Engineering. 18(1), 119-122. DOI: 10.24425/118823.

[14] Tsakiris, V. & Edmonds, D.V. (1999). Martensite and deformation twinning in austenitic steels. Materials Science and Engineering. 273-275, 430-436. DOI: 10.1016/S0921-5093(99)00322-6.

[15] Karaman, I., Sehitoglu, H., Gall, K., Chumlyakov, Y.I. & Maier, H.J. (2000). Deformation of single crystal Hadfield steel by twinning and slip. Acta Materialia. 48(6), 1345-1359. DOI: 10.1016/S1359-6454(99)00383-3.

[16] Bańkowski, D., Młynarczyk, P. S., Depczyński, W. & Bolanowski, K. C. (2024). The effect of work hardening on the structure and hardness of hadfield steel. Archives of Foundry Engineering. 24(1), 14-20. DOI: 10.24425/afe.2024.149246.

[17] Stradomski, Z. (2010). Microstructure in wear issues of wear-resistant steels. Częstochowa: Wydawnictwo Politechniki Częstochowskiej. (in Polish).

[18] Tęcza, G. & Głownia, J. (2015). Resistance to abrasive wear and volume fraction of carbides in cast high-manganese austenitic steel with composite structure. Archives of Foundry Engineering. 15(4), 129-133. DOI: 10.1515/afe-2015-0092.

[19] Maouche, H., Hadji, A. & Bouhamla, K. (2016). Effect of inoculation by molybdenum and nickel on hardening phenomenon and wear behavior of high manganese steel. Metallurgical and Mining Industry. 3, 75-82.

[20] Tęcza, G. (2022). Changes in microstructure and abrasion resistance during miller test of hadfield high-manganese cast steel after the formation of vanadium carbides in alloy matrix. Materials. 15(3), 1021, 1-11. DOI: 10.3390/ma15031021.

[21] Tęcza, G. (2021). Changes in abrasive wear resistance during miller test of high-manganese cast steel with niobium carbides formed in the alloy matrix. Applied Sciences. 11(11), 4794, 1-10. DOI: 10.3390/app11114794.

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Published

2025-09-30

How to Cite

Tęcza, Grzegorz, et al. “The Effect of Heat Treatment on the Microstructure and Hardness of an Austenitic Matrix of High-Manganese Cast Steel With the Addition of Molybdenum”. Archives of Foundry Engineering, vol. 25, no. 3, Sept. 2025, pp. 27-34, doi:10.24425/afe.2025.155351.

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