Experimental investigation of the performance and emission characteristics of cotton seed biodiesel / diesel blends with titanium dioxide nanoparticles

Authors

  • Santhosh Kumar Dubba Aditya Institute of Technology and Management, Tekkali 532201, Andhrapradesh, India; Indian Institute of Technology, Roorkee 247667, Uttarakhand, India
  • Raminaidu Pisini Aditya Institute of Technology and Management, Tekkali 532201, Andhrapradesh, India
  • Durgaprasad Kelli Aditya Institute of Technology and Management, Tekkali 532201, Andhrapradesh, India
  • Roopsandeep Bammidi Aditya Institute of Technology and Management, Tekkali 532201, Andhrapradesh, India
  • Jaya Prasad Vanam Jawaharlal Nehru Technological University, Kakinada 533003, Andhrapradesh, India
  • Narayana Turali Aditya Institute of Technology and Management, Tekkali 532201, Andhrapradesh, India

DOI:

https://doi.org/10.24425/ather.2025.156587

Abstract

This study uniquely investigates cotton seed oil as a biodiesel source, a less-explored feedstock, and evaluates the role of TiO2 nanoparticles in enhancing performance and emission characteristics. The use of a variable compression ratio engine under diverse load conditions further distinguishes this work from existing studies on nanoparticle-blended biofuels. The biodiesel was produced via transesterification and blended at various proportions, with and without TiO2 additives. Experimental tests were conducted on a variable compression ratio diesel engine under varying load conditions: one-fourth, half, three-fourths, and full load. The results were compared against conventional diesel fuel. Among the tested blends, B40 (40% biodiesel, 60% diesel) without TiO2 exhibited the highest brake thermal efficiency, exceeding that of diesel by 5.4%, and achieved the highest mechanical efficiency (58.31%) at full load condition. Fuel consumption increased proportionally with load across all fuel types. Notably, B40 without TiO2 also recorded the lowest hydrocarbon emissions, with a reduction of 34 ppm at full load, which corresponds to a 45% decrease compared to conventional diesel. Carbon monoxide emissions were effectively eliminated in TiO2-blended fuels due to improved combustion. Additionally, nitrogen oxides emissions were reduced by 1.1% in B40 when TiO2 was incorporated. Overall, the findings highlight that cotton seed biodiesel, particularly when enhanced with TiO2 nanoparticles, can offer substantial improvements in engine performance and emission control compared to conventional diesel.

References

[1] Bilal Ameer, H.M., Ameer, M.F., Ghachem, K., Ali, M., Razaq, A., Khan, S.U., Hamza, M., & Kolsi, L. (2022). Experimental comparison of performance and emission characteristics of 4-stroke CI engine operated with Roselle and Jatropha biodiesel blends. Journal of the Indian Chemical Society, 99(6), 100505. doi: 10.1016/j.jics.2022.100505

[2] Doğan, B., Yeşilyurt, M.K., Yaman, H., Korkmaz, N., & Arslan, A. (2024). Comprehensive analysis of a CI engine fuelled with blends of diesel fuel/safflower seed oil biodiesel/TiO2 or SiO2 nanoparticles produced by green synthesis technique. Process Safety and Environmental Protection, 191, 417–438. doi: 10.1016/j.psep.2024.08.104

[3] Kailash, M.N., & Murali, G. (2024). Solar energy powered biodiesel synthesis from linseed oil – A novel experimental study. Journal of the Indian Chemical Society, 101, 101259. doi: 10.1016/j.jics.2024.101259

[4] Kanimozhi, B., Karthikeyan, L., Praveenkumar, T.R., Alharbi, S.A., Alfarraj, S., & Gavurová, B. (2023). Evaluation of karanja and safflower biodiesel on engine’s performance and emission characteristics along with nanoparticles in DI engine. Fuel, 352, 129101. doi: 10.1016/j.fuel.2023.129101

[5] Manap, M.R.A., Baharim, H.I., Shamsudin, N.A.A., & Ferdaus, A.F. (2024). Dataset of NIR, MIR and FIR spectroscopy of fuels in maritime cases and biodiesel–diesel blends B7 and B10 from Malaysia. Data in Brief, 55, 110615. doi: 10.1016/j.dib.2024.110615

[6] Adebisi, A., Abd-Rasheed, A., Olusegun, T., Sanni, S.E., Oguntade, T., & Oni, B.A. (2023). Effects of hydrogen enrichment on diesel engine fueled with Afzelia Africana biodiesel – TiO2 blends. Egyptian Journal of Petroleum, 32(1), 81–86. doi: 10.1016/j.ejpe.2023.02.002

[7] Anjum, S.S., Prakash, O., Ahmad, S.N., & Pal, A. (2022). Optimization of biodiesel production from Argemone mexicana oil using Taguchi model. Proceedings of the Institution of Mechanical Engineers, Part E: Journal of Process Mechanical Engineering, 236(4), 1628–1636. doi: 10.1177/09544089221074839

[8] Dubba, S.K., & Kumar, R. (2017). Flow of refrigerants through capillary tubes: A state-of-the-art. Experimental Thermal and Fluid Science, 81, 370–381. doi: 10.1016/j.expthermflusci.2016.09.012

[9] Joshi, J.R., Bhanderi, K.K., & Patel, J.V. (2023). Waste cooking oil as a promising source for bio lubricants – A review. Journal of the Indian Chemical Society, 100, 100820. doi: 10.1016/j.jics.2022.100820

[10] Nyorere, O., Oluka, S.I., Onoji, S.E., Nwadiolu, R., & Adepoju, T.F. (2024). Dataset on acido-biocatalysis of agro solid wastes in acidic medium for the conversion of pink solo Carica papaya seed oil to biodiesel fuel. Data in Brief, 53, 110219. doi: 10.1016/j.dib.2024.110219

[11] Nawaz, I.S.S., & Asokan, M.A. (2025). Numerical and experimental analysis on titanium aluminide and yttria stabilized zirconia coated piston on gulmohar biodiesel/diesel blend: An RSM approach. Proceedings of the Institution of Mechanical Engineering, Part C: Journal of Mechanical Engineering Science, 239(15). doi: 10.1177/09544062251333992

[12] Thangamani, J., Ismailgani, R., & Arunagirinathan, K. (2024). Toward sustainable transportation: Experimental insights into Chlorella vulgaris algae biodiesel with titanium oxide nano-enhancement. Proceedings of the Institution of Mechanical Engineering, Part E: Journal of Process Mechanical Engineering. doi: 10.1177/09544089241277707

[13] Singh, M., Saini, P., Divyanshi, S., Mishra, S., & Ahmad, S.N. (2025). Effect of n-pentanol with novel water hyacinth biodiesel–diesel ternary blends on diesel engine performance and emission characteristics. Vietnam Journal of Chemistry, 62(6), 780–791. doi: 10.1002/vjch.202300383

[14] Alabi, O.O., Gbadeyan, O.J., Bala, A., Ogunsiji, G.O., & Deenadayalu, N. (2024). Study of combustion characteristics of diesel-vegetable oil blends utilizing an industrial fuel burner. Fuel Communications, 18, 100104. doi: 10.1016/j.jfueco.2023.100104

[15] Krupakaran, R.I., Hariprasad, T., & Gopalakrishna, A. (2019). Experimental investigation on direct injection diesel engine fuelled with addition of titanium dioxide nanoparticle to M. elangi biodiesel for varying injection pressures. Environmental Progress & Sustainable Energy, 38(5), 13207. doi: 10.1002/ep.13207

[16] Jain, A., Bora, B.J., Kumar, R., Barik, D., Kumar, N., Paramasivam, P., Kumar, R., Chohan, J.S., Majdi, H.S., Alsubih, M., Islam, S., Prakash, C., & Kumar, R. (2025). Assessment of Nahar biodiesel with TiO2 nanoparticles at increased fuel injection pressure of a diesel engine: Exergy, energy, statistical analysis. Case Studies in Thermal Engineering, 71, 106125. doi: 10.1016/j.csite.2025.106125

[17] Musthafa, M.M., Kumar, T.A., Mohanraj, T., & Chandramouli, R. (2018). A comparative study on performance, combustion and emission characteristics of diesel engine fuelled by biodiesel blends with and without an additive. Fuel, 225, 343–348. doi: 10.1016/j.fuel.2018.03.147

[18] Shaik, J.H., Khayum, N., & Pandey, K.K. (2025). Analysis of combustion characteristics of a diesel engine run on ternary blends using machine learning algorithms. Environmental Progress & Sustainable Energy, 44(3), e14582. doi: 10.1002/ep.14582

[19] Radhakrishnan Lawrence, K., Tharigonda, H., & Alluru, G. (2020). Experimental investigations on combined effect of EGR and SCR for diesel engine fuelled with the addition of TiO2 nanoparticle to M. Elangi methyl ester blend. Australian Journal of Mechanical Engineering, 18(2), 220–233. doi: 10.1080/14484846.2018.1519053

[20] Keskin, A., Yaşar, A., Yildizhan, Ş., Uludamar, E., Emen, F.M., & Külcü, N. (2018). Evaluation of diesel fuel-biodiesel blends with palladium and acetylferrocene based additives in a diesel engine. Fuel, 216, 349–355. doi: 10.1016/j.fuel.2017.11.154

[21] Jiaqiang, E., Zhang, Z., Chen, J., Pham, M., Zhao, X., Peng, Q., Zhang, B., & Yin, Z. (2018). Performance and emission evaluation of a marine diesel engine fueled by water biodiesel-diesel emulsion blends with a fuel additive of a cerium oxide nanoparticle. Energy Conversion and Management, 169, 194–205. doi: 10.1016/j.enconman.2018.05.073

[22] Mehregan, M., & Moghiman, M. (2018). Effects of nano-additives on pollutants emission and engine performance in a urea-SCR equipped diesel engine fueled with blended biodiesel. Fuel, 222, 402–406. doi: 10.1016/j.fuel.2018.02.172

[23] Soudagar, M.E.M., Nik-Ghazali, N.-N., Kalam, M.A., Badruddin, I.A., Banapurmath, N.R., & Akram, N. (2018). The effect of nano-additives in diesel-biodiesel fuel blends: A comprehensive review on stability, engine performance and emission characteristics. Energy Conversion and Management, 178, 146–177. doi: 10.1016/j.enconman.2018.10.019

Downloads

Published

2025-09-30

How to Cite

Kumar Dubba, Santhosh, et al. “Experimental Investigation of the Performance and Emission Characteristics of Cotton Seed Biodiesel Diesel Blends With Titanium Dioxide Nanoparticles”. Archives of Thermodynamics, vol. 46, no. 3, Sept. 2025, pp. 151-6, doi:10.24425/ather.2025.156587.

Issue

Section

Articles

Similar Articles

<< < 1 2 3 4 5 > >> 

You may also start an advanced similarity search for this article.