Development of a Measurement and Control Method Enabling the Determination of the Gas Phase Content in a Liquid Metal or Alloy

Authors

  • A.W. Bydalek University of Zielona Góra, Poland
  • S. Biernat Technical School Complex - Center for Vocational and Continuing Education in Leszno, Poland

DOI:

https://doi.org/10.24425/afe.2026.157988

Abstract

This article presents various possibilities for testing the degree of gassed of liquid metals. This phenomenon poses a significant problem in the foundry industry, therefore, it is crucial to conduct extraction processes and develop a rapid and accurate method for assessing the gas phase content in the alloy. In addition to analysing methods already known and used in industry and laboratories, the authors present possible research directions using innovative ideas. To confirm hypotheses, they build a test rig and then conduct a series of tests that yield interesting results. The authors studied a lead alloy (Pb-Sn). The alloy was analyzed under the same conditions, subjecting it to moderate and then intense gassed. The results were compared with those of a reference test of a ungassed alloy. It was observed that the ungassed alloy showed a linear increase in the resistance of the liquid metal over the tested temperature range. With the gassed charge, there were either slight changes or the resistance value remained constant over the tested temperature range. The research method not only provides a quick answer but also allows for determining whether the degassing process can be interrupted or should be continued. The method is based on examining the micro-resistance of the system at a given temperature using measuring probes placed in the liquid alloy. By examining a reference sample and determining its reference system parameters, the user can quickly assess the charge in terms of the degree of gassed for each subsequent batch of material prepared in the industrial process.

References

[1] Bonderek, Z., Rzadkosz, S. & Smorawiński, Z. (1999). Studies on the effectiveness of gas refining process. Solidification of Metals and Alloys. 1(41), 212 - 217.

[2] Pigoń, K., Ruziewicz, Z. (2005). Physical chemistry. Warsaw PWN. (in Polish).

[3] Dudyk, M. & Madej, J. (2010). The influence of purifying processes on crystallization and quality of aluminium casting. Acta Mechanica et Automatica, 4(3), 36-39. (in Polish).

[4] Rutkowski, K. (1977). Patent No. 108816. Kraków, Wydawnictwo Urzędu Patentowego Polskiej Rzeczypospolitej Ludowej, Warszawa.

[5] Bydałek, A.W., Bydałek, A., Biernat, S. (2017). Analysis of melting processes and measurements in metallurgy. PWSZ Głogów. (in Polish).

[6] Yang, J. & Liu, B. & Shu, D. & Li, H. & Yang, Q., Hu, T., Wang, Z., Zeng, Y., Huang, J. & Tang, X. (2025). Effect of ultra vacuum assisted high pressure die casting on the mechanical properties of Al-Si-Mn-Mg alloy. Journal of Alloys and Compounds. 1026, 180531, 1-13. DOI: 10.1016/j.jallcom.2025.180531 DOI: https://doi.org/10.1016/j.jallcom.2025.180531

[7] Bai, W. & Xu, Q. & Han, Z. & Chen, B. & Zhao, H. (2025). Mechanical and thermal performance enhancement of the vacuum-assisted die-casting Al80Si8Mg4Cu4Zn4 alloys via heat treatment. Materials Science and Engineering: A. 943, 148742, 1-19. DOI: 10.1016/j.msea.2025.148742. DOI: https://doi.org/10.1016/j.msea.2025.148742

[8] Cong, W. & Wang, F. & Du, X. & Wang, Z. & Zhou, L., Wei, Z., Mao, P. & Li, J. (2025). Study on microstructure, mechanical properties and thermal conductivity of vacuum-assisted high pressure die casting Mg-5Zn-xCu-0.5 Zr alloy. Materials Science and Engineering: A. 938, 148478, 1-13. DOI: 10.1016/j.msea.2025.148478. DOI: https://doi.org/10.1016/j.msea.2025.148478

[9] Rutkowski, K. & Karolini, M. & Miętka, Z. (1973). Slag coating for copper alloys. Instytut Odlewnictwa STOP Kraków. (in Polish).

[10] Olesz, M., & Ryl, J. (2013). Electrical resistance measurements of selected conductors. Zeszyty Naukowe Wydziału Elektrotechniki I Automatyki Politechniki Gdańskiej. 35, 35 – 38. (in Polish).

[11] Knych, T. (2014). Copper in Electrical Engineering. Research Report – Copper Resistivity Testing in the Temperature Range from 20 to 9000 C. AGH Kraków. (in Polish).

[12] Czujniki, Sterowniki. (2025). Retrieved September 28 , 2025, from: https://czujnikisterowniki.pl/pl/c/Przeplywy/37

[13] Królikowski, M. & Burbelko, A. & Kwaśniewska – Królikowska, D. (2014). X-Ray computed tomography in the nondestructive testing of ductile iron Castings. Archives of Foundry Engineering, 15 (4), 71-76. (in Polish).

[14] Biernat, S., Bydałek, A., Grabian, J. (2024). Patent No. P.448092. Urząd Patentowy Rzeczypospolitej Polskiej.

[15] Biernat, S. & Bydałek, A. (2019). Integrated analytical and measurement system for the evaluation of the properties of cast metals and alloys. Archives of Foundry Engineering. 19(1), 13-18. DOI: 10.24425/afe.2018.125184. DOI: https://doi.org/10.24425/afe.2018.125184

[15] Zuccolo, R. (2022). Effects of hydrogen and bifilm concentrations on the porosity and mechanical properties of an AlSi11(Fe) foundry alloy. Master's thesis, Universita Degli Studi di Padova, Padua, Italy.

[16] Chakrabarti, A.K. (2022).Casting technology and cast alloys (2nd ed.). PHI Learning Private Limited, Delhi.

[17] Liu, G., Ren, Y., Ma, W., Morita, K., Lei, Y., Zhan, S., Lv, G., Lu, S., Wang, Z. & Li, R. (2024). Recent advances and future trend of aluminum alloy melt purification: A review. Journal of Materials Research and Technology. 28, 4647-4662. DOI: 10.1016/j.jmrt.2024.01.024. DOI: https://doi.org/10.1016/j.jmrt.2024.01.024

[18] Krishnamurthi, V., Parker, C. J., Nguyen, C. K., Vaillant, P. H., Hocking, R. K., Haas, B., Christofferson, A.J., Russo, S.P., Chiang, A.W. & Daeneke, T. (2024). A toolbox for investigating liquid metal systems. Cell Reports Physical Science. 5(2), 1-37. DOI: 10.1016/j.xcrp.2024.101820 DOI: https://doi.org/10.1016/j.xcrp.2024.101820

[19] Li, Q., Ghadiani, H., Jalilvand, V., Alam, T., Farhat, Z., & Islam, M. A. (2024). Hydrogen impact: a review on diffusibility, embrittlement mechanisms, and characterization. Materials. 17(4), 965, 1-42. DOI: 10.3390/ma17040965 DOI: https://doi.org/10.3390/ma17040965

Downloads

Published

2026-07-13

How to Cite

Bydalek, A.W., and S. Biernat. “Development of a Measurement and Control Method Enabling the Determination of the Gas Phase Content in a Liquid Metal or Alloy”. Archives of Foundry Engineering, vol. 26, no. 2, July 2026, pp. 42-48, doi:10.24425/afe.2026.157988.

Issue

Section

Articles

Similar Articles

1 2 > >> 

You may also start an advanced similarity search for this article.